Standard difficulty · 20 questions · 40 marks
Show your working for Sections B and C. Answers are on the last page — try every question first!
Atoms · AW-12P-ATM-2026-V1 · For parents — fold back or tear off before handing the sheet to your child.
| Q | Answer | Working |
|---|---|---|
| 1 | (d) 4.77 Å | rn = n2r1/Z = 32 × 0.53/1 |
| 2 | (a) −4.896 eV | En = −13.6Z2/n2 eV with Z = 3 |
| 3 | (d) 1.89 eV | 13.6(1/22 − 1/32) |
| 4 | (d) 0.85 eV | 13.6 × 12/42 |
| 5 | (c) most of the atom is empty space | — |
| 6 | (a) 15 | n(n − 1)/2 |
| 7 | (b) Pfund series (infrared) | lines ending on n = 5 make the Pfund series |
| 8 | (c) A is true, but R is false. | A is true: En = −13.6/62 = −0.38 eV. R is false. |
| 9 | KE = 1.51 eV; PE = −3.02 eV; total = −1.51 eV | KE = −E, PE = 2E, E = −13.6Z2/n2 |
| 10 | 1.23 eV; 1,005.22 nm | ΔE = 13.6(1/32 − 1/72); λ = 1240/ΔE |
| 11 | 18.72 fm | K = k(2e)(Ze)/d ⇒ d = 1.44 × 2 × 13/2 |
| 12 | 8.72 × 105 m/s; 6.625 Å | vn = Zv1/n; rn = n2r1/Z |
| 13 | radii 25 : 16; energies 16 : 25 | r ∝ n2, E ∝ 1/n2 |
| 14 | 13.06 eV; 5h/(2π) | ΔE = 13.6(1/12 − 1/52); L = nh/2π |
| 15 | longest 1,864.97 nm; shortest 569.85 nm | longest: n = 6 → 5; shortest: n = ∞ → 5; energies × Z2 = 4 |
| 16 | 36 lines; n = 9 → 8 | the smallest energy gap gives the longest wavelength |
| 17 | n = 6; 3→2: 1.89 eV, 4→2: 2.55 eV, 5→2: 2.856 eV, 6→2: 3.02 eV, 4→3: 0.66 eV, 5→3: 0.97 eV, 6→3: 1.13 eV, 5→4: 0.306 eV, 6→4: 0.47 eV, 6→5: 0.17 eV | −13.6/22 + 3.02 = −13.6/n2 |
| 18 | 0.57 eV; 2,166.13 nm; Brackett; longest 4,052.29 nm | λ = 1240/ΔE |
| 19 | 37.92 fm and 75.84 fm; the nucleus must be smaller than these distances, so it is only a few tens of femtometres across at most | d = 2Zke2/K |
| 20 | 2.12 Å; 1.09 × 106 m/s; −3.4 eV; 3.4 eV | rn = n2r1/Z; vn = Zv1/n; En = Z2E1/n2 |