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Class 11 Organic Chemistry – Some Basic Principles and Techniques worksheet

CBSE Chemistry. IUPAC names, isomerism, electronic effects, intermediates, estimation of elements. Every sheet has 20 questions in three sections and an answer key, and the numbers change every time.

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Sample questions

Real questions from this chapter, as the app sets them. Tap Answer to see the answer and working.

Section A · multiple choice

  1. 1.

    The ability of carbon to form long chains by bonding to itself is called:

    1. isomerism
    2. resonance
    3. hybridisation
    4. catenation
    Answer

    (d) catenation

  2. 2.

    The IUPAC name of CH₂=CHCH₃ is:

    1. 2-methylpropene
    2. propan-1-amine
    3. propene
    4. 2-methylpropan-1-ol
    Answer

    (c) propene

    longest chain, lowest locants, functional group as suffix

  3. 3.

    CH₃CH₂CHO belongs to the class:

    1. ether
    2. alkane
    3. ketone
    4. aldehyde
    Answer

    (d) aldehyde

    look at the functional group

Section B · short answer

  1. 4.

    What is the difference between homolytic and heterolytic cleavage?

    Answer

    In homolytic cleavage each atom keeps one electron of the bond, giving free radicals. In heterolytic cleavage one atom takes both electrons, giving a cation and an anion (for carbon, a carbocation or a carbanion).

  2. 5.

    3 g of an organic compound gave 6.6 g of CO₂ and 3.6 g of H₂O on complete combustion. Find the percentages of carbon and hydrogen in it. (2 decimal places where needed.)

    Answer

    C 60%; H 13.33% (it is propan-1-ol)

    %C = 12 × mass CO₂ × 100/(44 × mass); %H = 2 × mass H₂O × 100/(18 × mass)

Section C · long answer

  1. 6.

    Explain the inductive effect, resonance effect, electromeric effect and hyperconjugation, with one example each.

    Answer

    Inductive: permanent σ-electron shift towards an electronegative atom; in CH₃CH₂Cl, chlorine pulls electrons from carbon. Resonance: delocalisation of π electrons or lone pairs through conjugation; in phenol the O lone pair spreads into the ring (+R). Electromeric: temporary complete π-electron shift when a reagent attacks a C=C or C=O. Hyperconjugation: delocalisation of C–H σ electrons into an adjacent empty p orbital or π bond; it makes (CH₃)₃C⁺ more stable than CH₃⁺.

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